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Table 6 The determination of fluoride-ions concentration and activity by the method of standard addition and modified method

From: Evaluation of free and total fluoride concentration in mouthwashes via measurement with ion-selective electrode

Label

pH

Dilution

F, mol/L × 10−3

Method of standard addition

Modified method

c (F)

a (F)

c (F)

a (F)

Colgate Total Plax

Classic mint

7.15

9.77

5.52

9.92

5.43

 

1÷10

0.75

0.89

1.11

1.06

Colgate Total Plax

Gentle mint

5.70

9.14

8.05

8.91

8.71

 

1÷10

1.22

0.75

1.19

1.20

Colgate Total Plax

Fresh mint

5.95

9.87

9.81

9.39

8.92

 

1÷10

0.63

0.47

0.70

0.43

Oral B Advantage

5.70

17.23

15.81

25.91

15.52

 

1÷10

1.42

1.21

1.2

0.98

Oral B Advantagea

5.75

16.70

12.30

16.81

6.08

Reach Fresh mint

5.80

15.86

14.56

24.09

13.71

 

1÷10

1.20

0.71

1.40

1.02

Reach Fresh minta

5.75

18.15

16.10

26.90

14.20

Foramen

5.80

14.62

9.11

20.05

9.05

 

1÷10

0.75

0.94

1.20

1.07

Lacalut sensitive

4.40

5.48

5.13

8.60

4.20

 

1÷10

0.758

0.77

0.15

0.86

Sensodyne

5.70

16.25

12.53

23.59

11.12

 

1÷10

2.01

1.27

Vesna F

6.05

4.49

2.76

5.20

2.71

Lacalut Fresh

4.20

0.093

1.30

0.095

 

1÷10

0.012

0.14

0.012

  1. a mouthwash of another batch was used